Phase-Transition-Enhanced Thermoelectric Transport in Rickardite Mineral Cu<sub>3–<i>x</i></sub>Te<sub>2</sub>
نویسندگان
چکیده
The binary copper chalcogenides Cu2??X (X = S, Se, and Te) have recently gained significant interest due to their high thermoelectric performance at moderate temperatures. In an effort unveil new Cu-based compounds with promising potential, Cu3–xTe2 rickardite mineral emerged as a candidate based on purely text mining approach applied by machine learning method. Polycrystalline samples of within the homogeneity range (x 0.1, 0.2) were successfully synthesized from raw elements solid-state High-temperature powder X-ray diffraction combined differential scanning calorimetry specific heat measurements showed several reversible phase transitions around 458, 640, 647 K. Signatures these observed electronic thermal transport properties, measured over broad temperatures (5–733 K). transition undergone this compound K results in crossover metallic-like semiconducting-like properties. combination power factor low conductivity high-temperature improved performances peak dimensionless figure-of-merit zT ?0.14 733 synthetic is exciting be used change material application areas such waste harvesting photovoltaic systems.
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ژورنال
عنوان ژورنال: Chemistry of Materials
سال: 2021
ISSN: ['1520-5002', '0897-4756']
DOI: https://doi.org/10.1021/acs.chemmater.0c04839